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delocalized electron : ウィキペディア英語版 | delocalized electron
In chemistry, delocalized electrons are electrons in a molecule, ion or solid metal that are not associated with a single atom or a covalent bond.〔IUPAC Gold Book (''delocalization'' )〕 The term is general and can have slightly different meanings in different fields. In organic chemistry, this refers to resonance in conjugated systems and aromatic compounds. In solid-state physics, this refers to free electrons that facilitate electrical conduction. In quantum chemistry, this refers to molecular orbitals that extend over several adjacent atoms. == Resonance == (詳細はsimple aromatic ring of benzene the delocalization of six π electrons over the C6 ring is often graphically indicated by a circle. The fact that the six C-C bonds are equidistant is one indication of this delocalization. In valence bond theory, delocalization in benzene is represented by resonance structures.
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